Composition of air
Air is a mixture of different gases. The gases that make up the air include nitrogen, oxygen, carbon dioxide, noble gases (argon, helium, neon, krypton and xenon) and a little water vapour. Air may also contain traces of impurities such as carbon monoxide (CO), sulphur dioxide (SO2), hydrogen sulphide (H2S) and other gases. The presence of these gases in air results in air pollution.
Table bellow shows the composition of air by volume. The
The Concept of Rusting
Explain the concept of rusting
Rusting
is the name given to the oxidation of iron or steel in damp air. It is
also called corrosion. Rust is hydrated iron (III) oxide. It is a soft,
crumbly solid and hence weakens the structure of iron and steel. During
rusting, iron reacts with oxygen to form brown iron (III) oxide
is the name given to the oxidation of iron or steel in damp air. It is
also called corrosion. Rust is hydrated iron (III) oxide. It is a soft,
crumbly solid and hence weakens the structure of iron and steel. During
rusting, iron reacts with oxygen to form brown iron (III) oxide

At the same time the iron (III) oxide reacts with water to form hydrated iron (III) oxide (or rust):

Note: The x in
the equation indicates that the number of water molecules in the
hydrated iron (III) oxide can vary. So, both oxygen and water are
needed to cause rusting of iron.
the equation indicates that the number of water molecules in the
hydrated iron (III) oxide can vary. So, both oxygen and water are
needed to cause rusting of iron.
Rusting
is a serious economic problem. Large sums of money are spent each year
to replace damaged iron and steel structures, or protecting structures
from such damages. Rusting of bridges, corrugated iron sheets on house
roofs, containers, articles, etc. require an expenditure of big sums of
money as well as labour for replacement. Rust weakens structures such as
car bodies, iron railings, and ships’ hulls, and shortens their useful
life. Preventing it can cost a lot of money. All efforts must be made to
stop iron or steel items from rusting. This can be achieved if we know
the conditions necessary for iron to rust.
is a serious economic problem. Large sums of money are spent each year
to replace damaged iron and steel structures, or protecting structures
from such damages. Rusting of bridges, corrugated iron sheets on house
roofs, containers, articles, etc. require an expenditure of big sums of
money as well as labour for replacement. Rust weakens structures such as
car bodies, iron railings, and ships’ hulls, and shortens their useful
life. Preventing it can cost a lot of money. All efforts must be made to
stop iron or steel items from rusting. This can be achieved if we know
the conditions necessary for iron to rust.
The Conditions Necessary for Iron to Rust
Demonstrate the conditions necessary for iron to rust
When
iron is left in contact with both water and oxygen (or air), it reacts
to form hydrated iron (III) oxide. Iron will not rust on exposure to dry
air or air-free water (water that has been boiled to expel all
dissolved air) only. However, iron will easily and readily rust in water
that has dissolved air in it. In figure 6.8, only the iron nail that is
in contact with both water and air rusts. Therefore, rusting will only
occur in the presence of both water and oxygen. If one of the two
conditions is excluded, in one way or another, rusting will not take
place at all.
iron is left in contact with both water and oxygen (or air), it reacts
to form hydrated iron (III) oxide. Iron will not rust on exposure to dry
air or air-free water (water that has been boiled to expel all
dissolved air) only. However, iron will easily and readily rust in water
that has dissolved air in it. In figure 6.8, only the iron nail that is
in contact with both water and air rusts. Therefore, rusting will only
occur in the presence of both water and oxygen. If one of the two
conditions is excluded, in one way or another, rusting will not take
place at all.
Testing for conditions necessary for iron rusting
Findings
Nails in tube 1 will rust. Nails in tubes 2 and 3 will not rust.
Reasons
In
tube 1, nails are in contact with both water and air (oxygen). In tube
2, the water has been boiled to expel the dissolved air. In addition,
any air above the water is prevented from dissolving in boiled water by a
layer of oil. So, the nails are completely shielded away from air.
Therefore, rusting is impossible. In tube 3, nails are in contact with
air only. The moisture present in air is absorbed by anhydrous calcium
chloride. Any moisture that might have been absorbed by the anhydrous
calcium chloride is prevented from reaching the nails by a tuft of
cotton wool. The cotton wool also absorbs some moisture directly from
the air. Therefore, tube 3 will always carry dry air (moisture-free
air). Hence, no rusting of iron nails occurs.
tube 1, nails are in contact with both water and air (oxygen). In tube
2, the water has been boiled to expel the dissolved air. In addition,
any air above the water is prevented from dissolving in boiled water by a
layer of oil. So, the nails are completely shielded away from air.
Therefore, rusting is impossible. In tube 3, nails are in contact with
air only. The moisture present in air is absorbed by anhydrous calcium
chloride. Any moisture that might have been absorbed by the anhydrous
calcium chloride is prevented from reaching the nails by a tuft of
cotton wool. The cotton wool also absorbs some moisture directly from
the air. Therefore, tube 3 will always carry dry air (moisture-free
air). Hence, no rusting of iron nails occurs.
This
experiment demonstrates the fact that for iron to rust, both water and
air (oxygen) must be present. If one of these conditions is controlled,
no rusting can take place.
experiment demonstrates the fact that for iron to rust, both water and
air (oxygen) must be present. If one of these conditions is controlled,
no rusting can take place.
Similarity between rusting and burning
Chemically,
rusting and burning are similar processes in that they both require
oxygen. Consider the burning of magnesium to give magnesium oxide.
rusting and burning are similar processes in that they both require
oxygen. Consider the burning of magnesium to give magnesium oxide.

In this process, magnesium combines with the oxygen of the air to form magnesium oxide.
During rusting, iron combines with oxygen of the air in the presence of water to form brown hydrated iron (III) oxide, “rust.”

In
addition, the two processes, burning and rusting, are exactly similar
in that they both generate heat. The only difference is in the time
required for each of the two processes to take place. During rusting
heat is given out, but without being noticed because of its slower rate
of production. Burning produces noticeable heat and light.
addition, the two processes, burning and rusting, are exactly similar
in that they both generate heat. The only difference is in the time
required for each of the two processes to take place. During rusting
heat is given out, but without being noticed because of its slower rate
of production. Burning produces noticeable heat and light.
The Different Methods of Preventing Iron from Rustin
Describe the different methods of preventing iron from rusting
We
have learned that for iron to rust there must be direct contact between
the iron and both water and oxygen from the air. Therefore, in order to
stop rusting we must protect iron from either water (moisture) or
oxygen (air) or both. The following are some of the methods used to
prevent iron from rusting:
have learned that for iron to rust there must be direct contact between
the iron and both water and oxygen from the air. Therefore, in order to
stop rusting we must protect iron from either water (moisture) or
oxygen (air) or both. The following are some of the methods used to
prevent iron from rusting:
Painting
Painting
the iron article creates a waterproof and airproof cover over the
surface of the iron. This method is widespread for objects ranging in
size from ships and bridges to garden gates. Paints that contain lead or
zinc are mostly used. These paints are especially good for preventing
rusting. For example, “red lead” paints contain an oxide of lead,.
the iron article creates a waterproof and airproof cover over the
surface of the iron. This method is widespread for objects ranging in
size from ships and bridges to garden gates. Paints that contain lead or
zinc are mostly used. These paints are especially good for preventing
rusting. For example, “red lead” paints contain an oxide of lead,.
As
oxygen and water cannot reach the iron, it does not rust. However, if
the paint layer is scratched off rusting may occur. So, regular
repainting is necessary to keep this protection intact.
oxygen and water cannot reach the iron, it does not rust. However, if
the paint layer is scratched off rusting may occur. So, regular
repainting is necessary to keep this protection intact.
Oiling and greasing
The
oiling and/or greasing of the moving parts of machinery forms a
protective film, preventing rusting. Moving parts cannot be painted
since the paint layer can be easily scratched off during movement.
Again, the treatment must be repeated to continue the protection.
oiling and/or greasing of the moving parts of machinery forms a
protective film, preventing rusting. Moving parts cannot be painted
since the paint layer can be easily scratched off during movement.
Again, the treatment must be repeated to continue the protection.
Plastic coating
Steel
is coated with plastic for use in garden chairs, refrigerators, bicycle
baskets, dish racks, etc. The plastic PVC (polyvinyl chloride), a trade
name for polychloroethene, is often used for this purpose. Plastic is
cheap and can be made to look attractive.
is coated with plastic for use in garden chairs, refrigerators, bicycle
baskets, dish racks, etc. The plastic PVC (polyvinyl chloride), a trade
name for polychloroethene, is often used for this purpose. Plastic is
cheap and can be made to look attractive.
Electroplating
Electroplating
is the coating of one metal with a layer of another metal by means of
electrolysis, where the metal to be coated is the cathode and the
coating metal the anode.
is the coating of one metal with a layer of another metal by means of
electrolysis, where the metal to be coated is the cathode and the
coating metal the anode.
An
iron or steel object can be electroplated with a layer of chromium or
tin to protect against rusting. A ‘tin can’ is made of steel coated on
both sides with a fine layer of tin. Tin is used because it is
unreactive and non-toxic. However, if protective layer is broken, then
the steel beneath will begin to rust. So, proper handling of tin-plated
items is needed.
iron or steel object can be electroplated with a layer of chromium or
tin to protect against rusting. A ‘tin can’ is made of steel coated on
both sides with a fine layer of tin. Tin is used because it is
unreactive and non-toxic. However, if protective layer is broken, then
the steel beneath will begin to rust. So, proper handling of tin-plated
items is needed.
Galvanizing
An iron object may be covered with a layer of zinc. This is called galvanizing.
Even if the zinc is scratched to expose the iron, the iron does not
rust. This is because zinc is higher in the reactivity series than iron.
So, zinc reacts with water and oxygen in preference to iron.
Even if the zinc is scratched to expose the iron, the iron does not
rust. This is because zinc is higher in the reactivity series than iron.
So, zinc reacts with water and oxygen in preference to iron.
The
zinc layer can be applied by several different methods. These include
electroplating or dipping the object into molten zinc. When an iron or
steel article is dipped into molten zinc and then removed, it becomes
coated with a thin layer of zinc. The zinc forms a protective coat over
the surface of iron. This process is used for dustbins, car bodies,
barbed wires and motorway crash barriers.
zinc layer can be applied by several different methods. These include
electroplating or dipping the object into molten zinc. When an iron or
steel article is dipped into molten zinc and then removed, it becomes
coated with a thin layer of zinc. The zinc forms a protective coat over
the surface of iron. This process is used for dustbins, car bodies,
barbed wires and motorway crash barriers.
Sacrificial protection
This
is a method of rust protection in which blocks of a metal more reactive
than iron are attached to the iron surface. Zinc and magnesium are more
reactive than iron. When blocks of zinc or magnesium are attached to
the hull of a steel ship or oil rig, it corrodes in preference to iron.
This is called sacrificial protection because the zinc or
magnesium is sacrificed to protect the iron. When the blocks are nearly
eaten away, they can be replaced by fresh blocks. Underground gas and
water pipes are connected by wire to blocks of magnesium to obtain the
same protection.
is a method of rust protection in which blocks of a metal more reactive
than iron are attached to the iron surface. Zinc and magnesium are more
reactive than iron. When blocks of zinc or magnesium are attached to
the hull of a steel ship or oil rig, it corrodes in preference to iron.
This is called sacrificial protection because the zinc or
magnesium is sacrificed to protect the iron. When the blocks are nearly
eaten away, they can be replaced by fresh blocks. Underground gas and
water pipes are connected by wire to blocks of magnesium to obtain the
same protection.
It
is not necessary to cover the whole surface of a steel article with the
more reactive metal for sacrificial protection to work. A ship may have
magnesium blocks riveted to its hull every few metres to prevent
rusting of the whole hull.
is not necessary to cover the whole surface of a steel article with the
more reactive metal for sacrificial protection to work. A ship may have
magnesium blocks riveted to its hull every few metres to prevent
rusting of the whole hull.
Blocks of zinc (or magnesium) attached to the hull of a ship
Alloying
Alloys
are mixtures of metals. For example, iron can be mixed with small
quantities of much less reactive metals to form an alloy called stainless steel.
Stainless steel contains iron mixed with chromium, nickel and
manganese. Stainless steel does not rust. It also has a very attractive
appearance. It is used to make cutlery and kitchen equipment.
are mixtures of metals. For example, iron can be mixed with small
quantities of much less reactive metals to form an alloy called stainless steel.
Stainless steel contains iron mixed with chromium, nickel and
manganese. Stainless steel does not rust. It also has a very attractive
appearance. It is used to make cutlery and kitchen equipment.
Use of silica gel
Silica is a common name for silicon dioxide (SiO2).
Silica gel is a granular, vitreous, highly porous form of silica made
synthetically from sodium silicate. Despite its name, silica gel is a
solid. It is used as a desiccant, which absorbs moisture to prevent
rusting of iron items or articles. Most often, a small bag of silica gel
is put inside bags or boxes used for storing or carrying iron items to
absorb any moisture that may cause rusting.
Silica gel is a granular, vitreous, highly porous form of silica made
synthetically from sodium silicate. Despite its name, silica gel is a
solid. It is used as a desiccant, which absorbs moisture to prevent
rusting of iron items or articles. Most often, a small bag of silica gel
is put inside bags or boxes used for storing or carrying iron items to
absorb any moisture that may cause rusting.
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